Yes. Goliath Performance Monitor supports monitors, alerts, and reports for Windows 365 Cloud PCs.
Figure: Cloud PC in the Goliath Dashboard - Status page
Cloud PCs health and performance metrics are displayed in the Goliath dashboards as well as more granular information for each individual Cloud PC in the Snapshot Metrics dialogs.
Refer to the Cloud PC configuration guide for additional details on how to enable monitoring of your Cloud PC environment.